Release of CNTs from textiles is possible during all life cycle stages (Koehler et al., 2008), however, there is currently no product on the market. A recent study has evaluated releases of CNTs by washing of cotton and polyester textiles (Goncalves et al., 2012). The release of inorganic nanomaterials from textiles during washing has been reported in several papers (Benn

and Westerhoff, 2008, Geranio et al., 2009, Lorenz et al., 2012 and Windler et al., 2012). Most studies were carried out with nano-Ag and found significant release into the washwater both as dissolved and particulate Ag (Benn and Westerhoff, PF-02341066 nmr 2008, Geranio et al., 2009 and Lorenz et al., 2012). However, washing out of Ag can involve dissolution of Ag + and precipitation as silver salts or re-formation of AgNPs by reduction of Ag + (Yin et al., 2012), processes not Ibrutinib manufacturer possible for CNTs and therefore the transferability of the Ag-results to CNTs may be limited. Most of the silver-textiles were also made using a finishing process and therefore the nano-Ag was only bound to the fiber surface and thus susceptible to release whereas fibers with nano-Ag embedded in the fiber released much lower amounts (Geranio et al., 2009). One study looked at releases of nano-TiO2, which is mainly incorporated into the fibers, therefore similar to a CNT-fiber composite, and it was found that

only very low amounts of TiO2 were released into washwater (Windler et al., 2012). We can therefore expect that release of CNTs from composite fibers will be relatively low, with some fraction released into washwater and therefore wastewater treatment plants. However, in washing liquid high concentrations of Lepirudin surfactants are present which are known to stabilize CNTs in suspension (Bouchard et al., 2012 and Schwyzer et al., 2011). Release of materials from nano-textiles can also occur during wearing the textiles and therefore consumer exposure is possible. Only two studies looking at consumer exposure to nano-Ag textiles

are available so far, however, they showed that mainly dissolution of nano-Ag occurred and the results are therefore not transferable to CNT-textiles (Kulthong et al., 2010 and Yan et al., 2012). Abrasion of CNTs during use by mechanical stress has however to be expected as textiles may lose up to 10% of their weight during use (Koehler et al., 2008). Normal ironing would not be expected to result in fiber release, however accidental burning by ironing may cause thermal degradation of the textile leaving an ash cake which contains free CNTs. Depending on the country, different percentages of textiles are collected and recycled, exported or disposed. A majority of the textiles are re-used or recycled (Koehler et al., 2008) creating potential occupational, consumer and environmental exposures.